Abstract:This study uses 9%Cr parent metal containing boron and 2.25%Cr weld metal to study the influence of long-term aging at elevated temperature on the carbon migration between the parent metal and weld metal. The size and number of precipitates in the carbon-enriched zone increase after long-term aging, but the precipitates in the carbon-denuded zone change little, which increases the differences in the mechanical properties between the carbon-enriched and carbon-denuded zones. Finite element analyses indicate that the carbon-denuded zone is damaged first by bearing loads with the damage increasing with long-term aging. Transmission electron microscope (TEM) pictures show that the precipitates at the grain boundaries of the heat affected zone in the 9%Cr parent metal change little, but precipitates inside the grains become coarse after long-term aging. Boron is responsible for the changes of the precipitates at grain boundaries and inside the grains, because the boron tends to segregate at the grain boundaries, which slows coarsening of the precipitates by occupying vacancies around the precipitates.
李克俭, 蔡志鹏, 李轶非, 胡梦佳, 潘际銮. 长期高温时效对有碳迁移发生的焊接接头的影响[J]. 清华大学学报(自然科学版), 2015, 55(10): 1051-1055.
LI Kejian, CAI Zhipeng, LI Yifei, HU Mengjia, PAN Jiluan. Influence of long-term aging at elevated temperature on welds with carbon migration. Journal of Tsinghua University(Science and Technology), 2015, 55(10): 1051-1055.
[1] Albert S K, Gills T P S, Tyagi A K, et al. Soft zone formation in dissimilar welds between two Cr-Mo steels [J]. Welding Journal: Welding Research Supplement, 1997, 76(3): 135-142.
[2] Lundin C D, Khan K K, Yang D. Effect of carbon migration in Cr-Mo weldments on metallurgical structure and mechanical properties: Report No. 1 [J]. WRC Bull, 1996, 407: 1-49.
[3] Inoue A, Masumoto T. Carbide reactions (M3C→ M7C3→ M23C6→ M6C) during tempering of rapidly solidified high carbon Cr-W and Cr-Mo steels [J]. Metallurgical Transactions A, 1980, 11(5): 739-747.
[4] Skleni?ka V, Kucha?ová K, Svoboda M, et al. Long-term creep behavior of 9%-12% Cr power plant steels [J]. Materials Characterization, 2003, 51(1): 35-48.
[5] 郑阳, 沈士明. Cr-Mo 钢焊接接头中碳迁移现象研究的现状与进展 [J]. 机械设计与制造工程, 2002, 31(1): 55-57.ZHENG Yang, SHEN Shiming. The current status and development of research on carbon migration in Cr-Mo steels weldment [J]. Machine Design and Manufacturing Engineering, 2002, 31(1): 55-57. (in Chinese)
[6] You Y Y, Shiue R K, Shiue R H, et al. The study of carbon migration in dissimilar welding of the modified 9Cr-1Mo steel [J]. Journal of Materials Science Letters, 2001, 20(15): 1429-1432.
[7] Pavlina E J, Van Tyne C J. Correlation of yield strength and tensile strength with hardness for steels [J]. Journal of Materials Engineering and Performance, 2008, 17(6): 888-893.
[8] Bao Y W, Wang W, Zhou Y C. Investigation of the relationship between elastic modulus and hardness based on depth-sensing indentation measurements [J]. Acta Materialia, 2004, 52(18): 5397-5404.
[9] Francis J A, Mazur W, Bhadeshia H. Review Type IV cracking in ferritic power plant steels [J]. Materials Science and Technology, 2006, 22(12): 1387-1395.
[10] Watanabe T, Tabuchi M, Yamazaki M, et al. Creep damage evaluation of 9Cr-1Mo-V-Nb steel welded joints showing Type IV fracture [J]. International Journal of Pressure Vessels and Piping, 2006, 83(1): 63-71.
[11] Shinozaki K, Li D, Kuroki H, et al. Observation of Type IV cracking in welded joints of high chromium ferritic heat resistant steels [J]. Science and Technology of Welding & Joining, 2003, 8(4): 289-295.
[12] 周振丰, 张文钺. 焊接冶金与金属焊接性 [M]. 北京: 机械工业出版社, 1988.ZHOU Zhenfeng, ZHANG Wenyue. Weld Metallurgy and Metal Weldability [M]. Beijing: China Machine Press, 1988. (in Chinese)
[13] Abe F, Tabuchi M, Tsukamoto S, et al. Microstructure evolution in HAZ and suppression of Type IV fracture in advanced ferritic power plant steels [J]. International Journal of Pressure Vessels and Piping, 2010, 87(11): 598-604.