Abstract：Uncatalysed oxidation of cyclohexane into cyclohexanone is dangerous since the process will explode when the tail oxygen volume fraction reaches a critical limit. Thus, the tail oxygen volume fraction needs to be well characterized for various operating parameters for safe production. A mathematical model of the reaction is given here as a function of the mass transfer rate, hydraulics and cyclohexane volatilization. The reaction kinetics and material balance model are also given. Simulations are then in good agreement with actual production data. The results show that when the gas phase oxygen volume fraction is 28% and the feed gas flow rate is 6 750 Nm3·h-1, the oxygen tail gas volume fraction increases to 3%, which will cause an explosion. The reaction temperature, the gas phase oxygen volume fraction and the feed gas flow rate are the most sensitive parameters in the reaction process, with the model providing a theoretical basis for controlling safe production of cyclohexanone.
李秀喜, 曹丽琦, 王兴. 环己烷氧化生产环己酮过程建模与参数分析[J]. 清华大学学报（自然科学版）, 2018, 58(5): 523-528.
LI Xiuxi, CAO Liqi, WANG Xing. Process modeling and analysis of the parameters for oxidation of cyclohexane into cyclohexanone. Journal of Tsinghua University(Science and Technology), 2018, 58(5): 523-528.
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2018, Vol. 58 
