Please wait a minute...
 首页  期刊介绍 期刊订阅 联系我们 横山亮次奖 百年刊庆
 
最新录用  |  预出版  |  当期目录  |  过刊浏览  |  阅读排行  |  下载排行  |  引用排行  |  横山亮次奖  |  百年刊庆
清华大学学报(自然科学版)  2022, Vol. 62 Issue (12): 2043-2052    DOI: 10.16511/j.cnki.qhdxxb.2022.25.049
  环境科学 本期目录 | 过刊浏览 | 高级检索 |
污染背景下的大气新粒子生成事件研究进展
尹扬娜1,2, 刘子锐1,2, 胡波1,2, 王跃思1,2
1. 中国科学院 大气物理研究所,北京 100029;
2. 中国科学院大学,北京 100049
Recent progress on the mechanisms of new particle formation and growth in polluted atmospheres
YIN Yangna1,2, LIU Zirui1,2, HU Bo1,2, WANG Yuesi1,2
1. Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing 100029, China;
2. University of Chinese Academy of Sciences, Beijing 100049, China
全文: PDF(6233 KB)   HTML
输出: BibTeX | EndNote (RIS)      
摘要 新粒子生成(new particle formation,NPF)是大气颗粒物的一个重要来源,对全球气候、区域环境质量乃至人体健康均有重要影响。过去几十年,随着新粒子及前体物监测仪器的不断发展,国内外研究者开展了一系列的外场观测实验来关注不同大气环境下的NPF事件。自从在污染大气背景下频繁观测到NPF事件以来,高凝结汇(condensation sink,CS)下的新粒子成核和增长机制逐渐成为国际大气化学领域的研究热点。该文梳理了近年来污染地区——以中国超大城市为代表的NPF研究进展,重点阐述了NPF事件发生和发展特征、诱发因素、成核机制以及贡献新粒子增长的关键化学组分,并进一步探讨了与区域NPF事件相关的气候效应和环境影响,结合当前研究现状对未来开展污染背景下新粒子事件研究的发展方向进行了展望。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
尹扬娜
刘子锐
胡波
王跃思
关键词 大气颗粒物新粒子生成(NPF)污染地区成核机制颗粒物增长    
Abstract:New particle formation (NPF) events are a key source of atmospheric aerosols which then profoundly influence the global climate, regional environmental quality and even human health. With the continuous development of both new particle and precursor monitoring instruments in the past few years, the literature has various field observations of NPF events in various atmospheric environments. In particular, NPF has occasionally been observed in polluted atmospheres in recent years, so the mechanism of new particles nucleation and growth in high concentration condensation sinks (CS) have gradually become much interest. This paper summarizes recent studies of NPF events in polluted areas in China and worldwide which emphasize the occurrence and development characteristics and factors inducing NPF events. This review also describes the formation mechanisms and the key chemical components contributing to growth, the climate effect and environmental impact, and the future research directions of the NPF events in polluted atmospheres based on the current research.
Key wordsatmospheric particulates    new particle formation (NPF)    polluted areas    nucleation mechanism    particles growth
收稿日期: 2021-07-22      出版日期: 2022-11-10
基金资助:刘子锐,研究员,E-mail:liuzirui@mail.iap.ac.cn
引用本文:   
尹扬娜, 刘子锐, 胡波, 王跃思. 污染背景下的大气新粒子生成事件研究进展[J]. 清华大学学报(自然科学版), 2022, 62(12): 2043-2052.
YIN Yangna, LIU Zirui, HU Bo, WANG Yuesi. Recent progress on the mechanisms of new particle formation and growth in polluted atmospheres. Journal of Tsinghua University(Science and Technology), 2022, 62(12): 2043-2052.
链接本文:  
http://jst.tsinghuajournals.com/CN/10.16511/j.cnki.qhdxxb.2022.25.049  或          http://jst.tsinghuajournals.com/CN/Y2022/V62/I12/2043
  
  
  
  
  
  
  
  
[1] KULMALA M, PETÄJÄ T, EHN M, et al. Chemistry of atmospheric nucleation: On the recent advances on precursor characterization and atmospheric cluster composition in connection with atmospheric new particle formation[J]. Annual Review of Physical Chemistry, 2014, 65: 21-37.
[2] DAL MASO M, KULMALA M, RⅡPINEN I, et al. Formation and growth of fresh atmospheric aerosols: Eight years of aerosol size distribution data from SMEAR Ⅱ, Hyytiala, Finland[J]. Boreal Environment Research, 2005, 10(5): 323-336.
[3] KULMALA M, LAAKSO L, LEHTINEN K E J, et al. Initial steps of aerosol growth[J]. Atmospheric Chemistry and Physics, 2004, 4(11-12): 2553-2560.
[4] RAO S, CHIRKOV V, DENTENER F, et al. Environmental modeling and methods for estimation of the global health impacts of air pollution[J]. Environmental Modeling & Assessment, 2012, 17(6): 613-622.
[5] SCHRAUFNAGEL D E. The health effects of ultrafine particles[J]. Experimental & Molecular Medicine, 2020, 52(3): 311-317.
[6] WANG Z B, WU Z J, YUE D L, et al. New particle formation in China: Current knowledge and further directions[J]. Science of the Total Environment, 2017, 577: 258-266.
[7] CHU B W, KERMINEN V M, BIANCHI F, et al. Atmospheric new particle formation in China[J]. Atmospheric Chemistry and Physics, 2019, 19(1): 115-138.
[8] NÉMETH Z, ROSATI B, ZíKOVÁ N, et al. Comparison of atmospheric new particle formation events in three Central European cities[J]. Atmospheric Environment, 2018, 178: 191-197.
[9] WU Z J. Variations and characteristics of fine and ultrafine particle number size distributions in the urban atmosphere of Beijing[D]. Beijing: Peking University, 2007. (in Chinese) 吴志军. 北京城市大气细和超细颗粒物数谱分布特征及变化规律[D]. 北京: 北京大学, 2007.
[10] KULMALA M, KERMINEN V M, PETÄJÄ T, et al. Atmospheric gas-to-particle conversion: Why NPF events are observed in megacities?[J]. Faraday Discussions, 2017, 200: 271-288.
[11] CAI R L, YANG D S, FU Y Y, et al. Aerosol surface area concentration: A governing factor in new particle formation in Beijing[J]. Atmospheric Chemistry and Physics, 2017, 17(20): 12327-12340.
[12] KUANG C, RⅡPINEN I, SIHTO S L, et al. An improved criterion for new particle formation in diverse atmospheric environments[J]. Atmospheric Chemistry and Physics, 2010, 10(17): 8469-8480.
[13] DENG C J, FU Y Y, DADA L, et al. Seasonal characteristics of new particle formation and growth in urban Beijing[J]. Environmental Science & Technology, 2020, 54(14): 8547-8557.
[14] PUSHPAWELA B, JAYARATNE R, MORAWSKA L. The influence of wind speed on new particle formation events in an urban environment[J]. Atmospheric Research, 2019, 215: 37-41.
[15] HUO J T, WANG X N, DUAN Y S, et al. First long-term study of atmospheric new particle formation in the suburb of Shanghai from 2015 to 2017[J]. Environmental Science, 2019, 40(11): 4791-4800. (in Chinese) 霍俊涛, 王新宁, 段玉森, 等. 2015—2017年上海郊区大气新粒子生成特征[J]. 环境科学, 2019, 40(11): 4791-4800.
[16] NIEMINEN T, MANNINEN H E, SIHTO S L, et al. Connection of sulfuric acid to atmospheric nucleation in boreal forest[J]. Environmental Science & Technology, 2009, 43(13): 4715-4721.
[17] WEBER R J, MCMURRY P H, MAULDIN R L, et al. New particle formation in the remote troposphere: A comparison of observations at various sites[J]. Geophysical Research Letters, 1999, 26(3): 307-310.
[18] ZHANG R Y, KHALIZOV A, WANG L, et al. Nucleation and growth of nanoparticles in the atmosphere[J]. Chemical Reviews, 2012, 112(3): 1957-2011.
[19] YANG S H, LIU Z R, CLUSIUS P S, et al. Chemistry of new particle formation and growth events during wintertime in suburban area of Beijing: Insights from highly polluted atmosphere[J]. Atmospheric Research, 2021, 255: 105553.
[20] YAO L, GARMASH O, BIANCHI F, et al. Atmospheric new particle formation from sulfuric acid and amines in a Chinese megacity[J]. Science, 2018, 361(6399): 278-281.
[21] WILDT J, MENTEL T F, KIENDLER-SCHARR A, et al. Suppression of new particle formation from monoterpene oxidation by NOx[J]. Atmospheric Chemistry and Physics, 2014, 14(6): 2789-2804.
[22] JAYARATNE R, PUSHPAWELA B, HE C R, et al. Observations of particles at their formation sizes in Beijing, China[J]. Atmospheric Chemistry and Physics, 2017, 17(14): 8825-8835.
[23] LV G L. Investigation of new particle formation in Jinan and at the summit of Mt. Tai[D]. Ji'nan: Shandong University, 2017. (in Chinese) 吕刚林. 济南市与泰山山顶大气新粒子形成研究[D]. 济南: 山东大学, 2017.
[24] XIAO S, WANG M Y, YAO L, et al. Strong atmospheric new particle formation in winter in urban Shanghai, China[J]. Atmospheric Chemistry and Physics, 2015, 15(4): 1769-1781.
[25] DAI L, WANG H L, ZHOU L Y, et al. Regional and local new particle formation events observed in the Yangtze River Delta region, China[J]. Journal of Geophysical Research: Atmospheres, 2017, 122(4): 2389-2402.
[26] QI X M, DING A J, ROLDIN P, et al. Modelling studies of HOMs and their contributions to new particle formation and growth: Comparison of boreal forest in Finland and a polluted environment in China[J]. Atmospheric Chemistry and Physics, 2018, 18(16): 11779-11791.
[27] KAMRA A K, SⅡNGH D, GAUTAM A S, et al. Atmospheric ions and new particle formation events at a tropical location, Pune, India[J]. Quarterly Journal of the Royal Meteorological Society, 2015, 141(693): 3140-3156.
[28] KANAWADE V P, TRIPATHI S N, SⅡNGH D, et al. Observations of new particle formation at two distinct Indian subcontinental urban locations[J]. Atmospheric Environment, 2014, 96: 370-379.
[29] PUSHPAWELA B, JAYARATNE R, MORAWSKA L. Temporal distribution and other characteristics of new particle formation events in an urban environment[J]. Environmental Pollution, 2018, 233: 552-560.
[30] CARNERERO C, PÉREZ N, RECHE C, et al. Vertical and horizontal distribution of regional new particle formation events in Madrid[J]. Atmospheric Chemistry and Physics, 2018, 18(22): 16601-16618.
[31] KALKAVOURAS P, BOUGIATIOTI A, GRIVAS G, et al. On the regional aspects of new particle formation in the Eastern Mediterranean: A comparative study between a background and an urban site based on long term observations[J]. Atmospheric Research, 2020, 239: 104911.
[32] KULMALA M, VEHKAMÄKI H, PETÄJÄ T, et al. Formation and growth rates of ultrafine atmospheric particles: A review of observations[J]. Journal of Aerosol Science, 2004, 35(2): 143-176.
[33] SHEN X J, SUN J Y, KIVEKÄS N, et al. Spatial distribution and occurrence probability of regional new particle formation events in eastern China[J]. Atmospheric Chemistry and Physics, 2018, 18(2): 587-599.
[34] YUE D L, ZHONG L J, SHEN J, et al. Parameter simulation and characterizations of new particle formation events in different seasons in the Pearl River Delta region[J]. China Sciencepaper, 2015, 10(21): 2500-2504, 2508. (in Chinese) 岳玎利, 钟流举, 沈劲, 等. 珠三角地区大气新粒子生成事件的参数模拟与特征[J]. 中国科技论文, 2015, 10(21): 2500-2504, 2508.
[35] LEE S H, GORDON H, YU H, et al. New particle formation in the atmosphere: From molecular clusters to global climate[J]. Journal of Geophysical Research: Atmospheres, 2019, 124(13): 7098-7146.
[36] WANG Z B, HU M, WU Z J, et al. Research on the formation mechanisms of new particles in the atmosphere[J]. Acta Chimica Sinica, 2013, 71(4): 519-527. (in Chinese) 王志彬, 胡敏, 吴志军, 等. 大气新粒子生成机制的研究[J]. 化学学报, 2013, 71(4): 519-527.
[37] HU M, SHANG D J, GUO S, et al. Mechanism of new particle formation and growth as well as environmental effects under complex air pollution in China[J]. Acta Chimica Sinica, 2016, 74(5): 385-391. (in Chinese) 胡敏, 尚冬杰, 郭松, 等. 大气复合污染条件下新粒子生成和增长机制及其环境影响[J]. 化学学报, 2016, 74(5): 385-391.
[38] LI Y F, ZHANG H J, ZHANG Q Z, et al. Interactions of sulfuric acid with common atmospheric bases and organic acids: Thermodynamics and implications to new particle formation[J]. Journal of Environmental Sciences, 2020, 95: 130-140.
[39] EHN M, THORNTON J A, KLEIST E, et al. A large source of low-volatility secondary organic aerosol[J]. Nature, 2014, 506(7489): 476-479.
[40] BERNDT T, RICHTERS S, KAETHNER R, et al. Gas-phase ozonolysis of cycloalkenes: Formation of highly oxidized RO2 radicals and their reactions with NO, NO2, SO2, and other RO2 radicals[J]. The Journal of Physical Chemistry A, 2015, 119(41): 10336-10348.
[41] JOKINEN T, BERNDT T, MAKKONEN R, et al. Production of extremely low volatile organic compounds from biogenic emissions: Measured yields and atmospheric implications[J]. Proceedings of the National Academy of Sciences of the United States of America, 2015, 112(23): 7123-7128.
[42] YU H, REN L L, KANAWADE V P. New particle formation and growth mechanisms in highly polluted environments[J]. Current Pollution Reports, 2017, 3(4): 245-253.
[43] LI H, NING A, ZHONG J, et al. Influence of atmospheric conditions on sulfuric acid-dimethylamine-ammonia-based new particle formation[J]. Chemosphere, 2020, 245: 125554.
[44] FANG X, HU M, SHANG D J, et al. Observational evidence for the involvement of dicarboxylic acids in particle nucleation[J]. Environmental Science & Technology Letters, 2020, 7(6): 388-394.
[45] WANG M Y, KONG W M, MARTEN R, et al. Rapid growth of new atmospheric particles by nitric acid and ammonia condensation[J]. Nature, 2020, 581(7807): 184-189.
[46] ZAMORA M L, PENG J F, HU M, et al. Wintertime aerosol properties in Beijing[J]. Atmospheric Chemistry and Physics, 2019, 19(22): 14329-14338.
[47] KANAWADE V P, TRIPATHI S N, CHAKRABORTY A, et al. Chemical characterization of sub-micron aerosols during new particle formation in an urban atmosphere[J]. Aerosol and Air Quality Research, 2020, 20(6): 1294-1305.
[48] KERMINEN V M, CHEN X M, VAKKARI V, et al. Atmospheric new particle formation and growth: Review of field observations[J]. Environmental Research Letters, 2018, 13(10): 103003.
[49] RⅡPINEN I, MANNINEN H E, YLI-JUUTI T, et al. Applying the condensation particle counter battery (CPCB) to study the water-affinity of freshly-formed 2-9 nm particles in boreal forest[J]. Atmospheric Chemistry and Physics, 2009, 9(10): 3317-3330.
[50] KUANG C, MCMURRY P H, MCCORMICK A V. Determination of cloud condensation nuclei production from measured new particle formation events[J]. Geophysical Research Letters, 2009, 36(9): L09822.
[51] ASMI E, KIVEKÄS N, KERMINEN V M, et al. Secondary new particle formation in Northern Finland Pallas site between the years 2000 and 2010[J]. Atmospheric Chemistry and Physics, 2011, 11(24): 12959-12972.
[52] WANG Z B, HU M, SUN J Y, et al. Characteristics of regional new particle formation in urban and regional background environments in the North China Plain[J]. Atmospheric Chemistry and Physics, 2013, 13(24): 12495-12506.
[53] YU H, ORTEGA J, SMITH J N, et al. New particle formation and growth in an isoprene-dominated ozark forest: From sub-5 nm to CCN-active sizes[J]. Aerosol Science and Technology, 2014, 48(12): 1285-1298.
[54] SHEN X J, SUN J Y, ZHANG X Y, et al. Key features of new particle formation events at background sites in China and their influence on cloud condensation nuclei[J]. Frontiers of Environmental Science & Engineering, 2016, 10(5): 5.
[55] ROSE C, SELLEGRI K, MORENO I, et al. CCN production by new particle formation in the free troposphere[J]. Atmospheric Chemistry and Physics, 2017, 17(2): 1529-1541.
[56] DE ESPAÑA C D, WONASCHVTZ A, STEINER G, et al. Long-term quantitative field study of new particle formation (NPF) events as a source of cloud condensation nuclei (CCN) in the urban background of Vienna[J]. Atmospheric Environment, 2017, 164: 289-298.
[57] MAKKONEN R, ASMI A, KERMINEN V M, et al. Air pollution control and decreasing new particle formation lead to strong climate warming[J]. Atmospheric Chemistry and Physics, 2012, 12(3): 1515-1524.
[58] GORDON H, KIRKBY J, BALTENSPERGER U, et al. Causes and importance of new particle formation in the present-day and preindustrial atmospheres[J]. Journal of Geophysical Research: Atmospheres, 2017, 122(16): 8739-8760.
[59] KAZIL J, STIER P, ZHANG K, et al. Aerosol nucleation and its role for clouds and Earth's radiative forcing in the aerosol-climate model ECHAM5-HAM[J]. Atmospheric Chemistry and Physics, 2010, 10(22): 10733-10752.
[60] YU F, LUO G, LIU X, et al. Indirect radiative forcing by ion-mediated nucleation of aerosol[J]. Atmospheric Chemistry and Physics, 2012, 12(23): 11451-11463.
[61] WESTERVELT D M, PIERCE J R, RⅡPINEN I, et al. Formation and growth of nucleated particles into cloud condensation nuclei: Model-measurement comparison[J]. Atmospheric Chemistry and Physics, 2013, 13(15): 7645-7663.
[62] PENG J F, HU M, SHANG D J, et al. Explosive secondary aerosol formation during severe haze in the North China plain[J]. Environmental Science & Technology, 2021, 55(4): 2189-2207.
No related articles found!
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
版权所有 © 《清华大学学报(自然科学版)》编辑部
本系统由北京玛格泰克科技发展有限公司设计开发 技术支持:support@magtech.com.cn