Research Article |
|
|
|
|
|
Preliminary design and energy analysis of a steelmaking system coupled with nuclear hydrogen based on a high-temperature gas-cooled reactor |
QU Xinhe, HU Qingxiang, NI Hang, PENG Wei, ZHAO Gang, WANG Jie |
Key Laboratory of Advanced Reactor Engineering and Safety of Ministry of Education, Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China |
|
|
Abstract [Objective] High-temperature gas-cooled reactors (HTGRs) have promising applications in the face of current environmental and energy problems due to their inherent safety and high reactor outlet temperature. They can be used not only for power generation but also for large-scale hydrogen production. Hydrogen can be used as a direct reducing agent in steelmaking, contributing to carbon reduction in the steel industry. It is necessary to study the coupling of HTGRs and the steelmaking system.[Methods] In this study, an HTGR-based steelmaking system is proposed, which includes five submodules:reactor module, reactor intermediate loop module, hydrogen production module, power generation module, and steelmaking module; then, a multi-generation energy system was investigated. In the reactor module, two HTGRs are connected in parallel as heat source, their thermal power is 250 MW, and the reactor outlet temperature is 950 ℃. The heat from the reactor module is transferred to the hydrogen generation module and the power generation module through an intermediate heat exchanger. The hydrogen generation module uses hydrothermal decomposition based on the iodine-sulfur process to generate hydrogen. The heat required for the iodine-sulfur process is provided by helium in the intermediate heat exchanger circuit and by the extracted steam from the power generation module. The hydrogen produced by the hydrogen production module is routed to a shaft furnace (SF) as the reductant and fuel for direct reduction ironmaking, and the oxygen produced by the hydrogen production module and the electricity produced by the power generation module are routed to an electric arc furnace (EAF) for steelmaking. The iodine-sulfur process efficiency, the power ratio of the power generation module to the reactor, the percentage of direct reduction iron in raw materials on the EAF system capacity, and the carbon emissions of the system are analyzed.[Results] In a steelmaking system with heat supplied by two 250 MW HTGRs, 1.35 t of iron ore is required to produce 1 t of steel when the power ratio of the power generation module and the hydrogen generation module is 1:1, the proportion of direct reduction iron in the raw material is 90%, and the iodine-sulfur process efficiency is 37.8%. Simultaneously, the system can deliver 63.0 MW (4.97 GJ for 1 t of steel) of electric energy to the power grid, and the steel production rate is 45.6 t/h. The parameter analysis shows that increasing the hydrogen production efficiency of the iodine-sulfur process can significantly increase the steel yield; however, the power consumption of the iodine-sulfur process module increases simultaneously, which reduces the output to the power grid. The steelmaking system proposed in this paper has very low CO2 emissions. When the proportion of directly reduced iron in the EAF is 90%, only 17.2 Nm3 (33.8 kg) of CO2 is emitted in producing 1 t of steel.[Conclusions] Therefore, coupling the HTGR hydrogen production with the steelmaking system has great application potential for significantly reducing the CO2 emissions of the steelmaking industry and eliminating the dependence on coke.
|
Keywords
nuclear hydrogen production
high-temperature gas-cooled reactor
iodine-sulfur process
steelmaking
|
Issue Date: 22 July 2023
|
|
|
[1] 国家统计局. 中华人民共和国2020年国民经济和社会发展统计公报[J]. 中国统计, 2021(3):6-9. National Bureau of Statistics of The People's Republic of China. Statistical communique of the People's Republic of China on the 2020 national economic and social development[J]. China Statistics, 2021(3):6-9. (in Chinese) [2] WANG R R, ZHAO Y Q, BABICH A, et al. Hydrogen direct reduction (HDR) in steel industry:An overview of challenges and opportunities[J]. Journal of Cleaner Production, 2021, 329:129797. [3] ABDIN Z, ZAFARANLOO A, RAFIEE A, et al. Hydrogen as an energy vector[J]. Renewable and Sustainable Energy Reviews, 2020, 120:109620. [4] ŞAHIN S, ŞAHIN H M. Generation-IV reactors and nuclear hydrogen production[J]. International Journal of Hydrogen Energy, 2021, 46(57):28936-28948. [5] 史力, 赵加清, 刘兵, 等. 高温气冷堆关键材料技术发展战略[J]. 清华大学学报(自然科学版), 2021, 61(4):270-278. SHI L, ZHAO J Q, LIU B, et al. Development strategy of key materials technology for the high temperature gas-cooled reactor[J]. Journal of Tsinghua University (Science and Technolgoy), 2021, 61(4):270-278. (in Chinese) [6] YAN X L, HINO R. Nuclear hydrogen production handbook[M]. Boca Raton:Taylor & Francis, 2011. [7] ZHANG P, WANG L J, CHEN S Z, et al. Progress of nuclear hydrogen production through the iodine-sulfur process in China[J]. Renewable and Sustainable Energy Reviews, 2018, 81:1802-1812. [8] ELDER R, ALLEN R. Nuclear heat for hydrogen production:Coupling a very high/high temperature reactor to a hydrogen production plant[J]. Progress in Nuclear Energy, 2009, 51(3):500-525. [9] KUNITOMI K, YAN X, NISHIHARA T, et al. JAEA's VHTR for hydrogen and electricity cogeneration:GTHTR300C[J]. Nuclear Engineering and Technology, 2007, 39(1):9-20. [10] SATO H, NOMOTO Y, HORII S, et al. HTTR-GT/H2 test plant-System performance evaluation for HTTR gas turbine cogeneration plant[J]. Nuclear Engineering and Design, 2018, 329:247-254. [11] BLICKWEDE D J, BARNHART T F. Use of nuclear energy in steelmaking:Prospects and plans[C]//Proceedings of the First National Topical Meeting on Nuclear Process Heat Applications. Los Alamos, USA:Los Alamos Scientific Lab, 1974:1-3. [12] VRABLE D L. High temperature heat exchange:Nuclear process heat applications[R]. San Diego:General Atomic Co., 1980. [13] INAGAKI Y, KASAHARA S, OGAWA M. Merit assessment of nuclear hydrogen steelmaking with very high temperature reactor[J]. ISIJ International, 2012, 52(8):1420-1426. [14] SHIMOKAWA K. Present status of research and development of nuclear steelmaking in Japan[J]. Transactions of the Iron and Steel Institute of Japan, 1979, 19(5):291-300. [15] TSURUOKA K, INATANI T, MIYASUGI T, et al. Design study of nuclear steelmaking system[J]. Transactions of the Iron and Steel Institute of Japan, 1983, 23(12):1091-1101. [16] TANAKA R, MATSUO T. Development of superalloys for intermediate heat exchanger tubes in national research and development program of nuclear steelmaking[J]. Tetsu-to-Hagane, 1982, 68(2):226-235. [17] ABE F, ARAKI H, YOSHIDA H, et al. Corrosion behavior of nickel base heat resisting alloys for nuclear steelmaking system in high-temperature steam[J]. Transactions of the Iron and Steel Institute of Japan, 1985, 25(5):424-432. [18] KASAHARA S, INAGAKI Y, OGAWA M. Flow sheet model evaluation of nuclear hydrogen steelmaking processes with VHTR-IS (very high temperature reactor and iodine-sulfur process)[J]. ISIJ International, 2012, 52(8):1409-1419. [19] YAN X L, KASAHARA S, TACHIBANA Y, et al. Study of a nuclear energy supplied steelmaking system for near-term application[J]. Energy, 2012, 39(1):154-165. [20] KASAHARA S, INAGAKI Y, OGAWA M. Process flow sheet evaluation of a nuclear hydrogen steelmaking plant applying very high temperature reactors for efficient steel production with less CO2 emissions[J]. Nuclear Engineering and Design, 2014, 271:11-19. [21] 那树人. 炼铁工艺学[M]. 北京:冶金工业出版社, 2014. NA S R. Ironmaking technology[M]. Beijing:Metallurgical Industry Press, 2014. (in Chinese) [22] 曲新鹤, 赵钢, 王捷, 等. 基于核能制氢的氢电联产系统能量梯级利用研究[J]. 原子能科学技术, 2021, 55(S1):37-44. QU X H, ZHAO G, WANG J, et al. Study on energy cascade utilization of hydrogen-electricity cogeneration system based on nuclear hydrogen production[J]. Atomic Energy Science and Technology, 2021, 55(S1):37-44. (in Chinese) [23] NI H, PENG W, QU X H, et al. Thermodynamic analysis of a novel hydrogen-electricity-heat polygeneration system based on a very high-temperature gas-cooled reactor[J]. Energy, 2022, 249:123695. [24] NI H, QU X H, PENG W, et al. Analysis of internal heat exchange network and hydrogen production efficiency of iodine-sulfur cycle for nuclear hydrogen production[J]. International Journal of Energy Research, 2022, 46(11):15665-15682. [25] 任素波, 白明华, 龙鹄, 等. 气基竖炉直接还原技术及仿真[M]. 北京:冶金工业出版社, 2018. REN S B, BAI M H, LONG H, et al. Direct reduction technology and simulation in gas-based shaft furnace[M]. Beijing:Metallurgical Industry Press, 2018. (in Chinese) [26] KIRSCHEN M, BADR K, PFEIFER H. Influence of direct reduced iron on the energy balance of the electric arc furnace in steel industry[J]. Energy, 2011, 36(10):6146-6155. [27] MERAIKIB M. Effects of sponge iron on the electric arc furnace operation[J]. ISIJ International, 1993, 33(11):1174-1181. [28] PARISI D R, LABORDE M A. Modeling of counter current moving bed gas-solid reactor used in direct reduction of iron ore[J]. Chemical Engineering Journal, 2004, 104(1-3):35-43. [29] KUROZU S, TAKAHASHI R, TAKAHASHI Y. Reduction rates of iron oxide pellet with mixtures of hydrogen and carbon monoxide at high pressures[J]. Tetsu-to-Hagane, 1980, 66(3):336-345. [30] HOLAPPA L. A general vision for reduction of energy consumption and CO2 emissions from the steel industry[J]. Metals, 2020, 10(9):1117. |
|
Viewed |
|
|
|
Full text
|
|
|
|
|
Abstract
|
|
|
|
|
Cited |
|
|
|
|
|
Shared |
|
|
|
|
|
Discussed |
|
|
|
|