结合中国废旧锂离子电池行业现状,采用知识产权分析方法对中国废旧锂离子电池资源回收技术发展趋势、核心技术区域、关键技术领域、主要技术发明人情况等进行了系统分析,并归纳总结了锂离子电池资源回收的核心技术要点,梳理出当前锂离子电池回收过程的技术路线分布状况。结果表明:近3年来,伴随着环保政策要求,锂离子电池回收专利文献数量进入了快速增长时期,专利年申请量已突破200件;技术分布于电气/冶金/化学/环保等领域,具有很强的学科领域交叉特性;申请机构中企业的高占比说明该技术的研究具有很强的工业应用价值。随着国家环保方面的政策日益完善和资源需求逐年提升,基于回收技术仍有较大进步空间,可以预测废旧锂离子电池的回收专利量会保持较大的上升趋势。产业政策、特别是污染防治规范与标准等将对相关技术研究与应用提供重要支撑。
Abstract
This study investigated the intellectual property concerns related to recycling spent lithium-ion batteries in China. This report summarizes the technical development trends, main regional distribution networks, critical technical fields, core technical points, and the core applicants. The results show that in the past 3 years, the number of patents related to lithium-ion battery recycling has increased rapidly to over 200 patents/a. There are many cross-disciplinary patents with many patents focused on the electrical components, metallurgy, chemistry, and environmental effects. The main applicants are not just limited to universities and research institutes, but also include a large number of companies since this research has significant industrial value. The stronger national environmental requirements and the increasing demand for resources is leading to many improvements in recycling methods as indicated by the increasing number of patents. Industrial policies, especially pollution prevention and control standards, provide important incentives for further research and for the development of improved recycling methods.
关键词
锂离子电池 /
专利 /
回收 /
技术路线 /
产业政策
Key words
lithium-ion batteries /
patent /
recycling /
technical roadmap /
industrial policy
{{custom_sec.title}}
{{custom_sec.title}}
{{custom_sec.content}}
参考文献
[1] WU F, YUSHIN G. Conversion cathodes for rechargeable lithium and lithium-ion batteries[J]. Energy & Environmental Science, 2017,10(2):435-459.
[2] 资源强制回收产业技术创新战略联盟. 关于举办2018年中国动力电池回收利用产业大会暨联盟年会的通知[C/OL]. (2018-10-23)[2019-02-28]. http://www.atcrr.org/show-19-3581-1.html. Alliance of Technological Innovation in Compulsory Resources Recycling Industry. Notice on holding the 2018 China electric vehicle battery recycling industry conference and alliance annual meeting[C/OL]. (2018-10-23)[2019-02-28]. http://www.atcrr.org/show-19-3581-1.html. (in Chinese)
[3] 宋佳丽, 孙峙, 高文芳等. 锂离子电池正极废料中有价元素选择性回收与动力学[J]. 过程工程学报, 2017,17(4):845-852. SONG J L, SUN Z, GAO W F, et al. Selective recovery and kinetics of valuable elements from waste lithium-ion battery cathodes[J]. Chinese Journal of Process Engineering, 2017, 17(4):845-852. (in Chinese)
[4] 林娇, 刘春伟, 曹宏斌等. 基于高温化学转化的废旧锂离子电池资源化技术进展[J]. 化学进展, 2018,30(9):1445-1454. LIN J, LIU C W, CAO H B, et al. Recovery of spent lithium ion batteries based on high temperature chemical conversion[J]. Process in Chemistry, 2018,30(9):1445-1454. (in Chinese)
[5] SONG J, YAN W, CAO H, et al. Material flow analysis on critical raw materials of lithium-ion batteries in China[J]. Journal of Cleaner Production, 2019, 215:570-581.
[6] 工业和信息化部, 科学技术部, 环境保护部等. 关于印发《新能源汽车动力蓄电池回收利用管理暂行办法》的通知[EB/OL]. (2018-02-26)[2019-02-01]. http://www.miit.gov.cn/n1146295/n1652858/n1652930/n3757016/c6068823/content.html. Ministry of Industry and Information Technology, Ministry of Science and Technology, Ministry of Science and Technology, etc. Notice on the issuance of interim measures for the management of the recovery and utilization of new energy vehicle power batteries[EB/OL]. (2018-02-26)[2019-02-01]. http://www.miit.gov.cn/n1146295/n1652858/n1652930/n3757016/c6068823/content.html. (in Chinese)
[7] PETERS J, WEIL M. A critical assessment of the resource depletion potential of current and future lithium-ion batteries[J]. Resources, 2016,5(4):46.
[8] ZENG X, LI J, Singh N. Recycling of spent lithium-ion battery:A critical review[J]. Critical Reviews in Environmental Science & Technology, 2014,44(10):1129-1165.
[9] LÜ W, WANG Z, CAO H, et al. A critical review and analysis on the recycling of spent lithium-ion batteries[J]. ACS Sustainable Chemistry & Engineering, 2018,6(2):1504-1521.
[10] 裴普成, 陈嘉瑶, 吴子尧. 锂离子电池自放电机理及测量方法[J]. 清华大学学报(自然科学版), 2019, 59(1):53-65. PEI P C, CHEN J Y, WU Z Y. Self-discharge mechanism and measurement methods for lithium ion batteries. Journal of Tsinghua University (Science and Technology), 2019, 59(1):53-65. (in Chinese)
[11] SUN H, GENG Y, HU L, et al. Measuring China's new energy vehicle patents:A social network analysis approach[J]. Energy, 2018,153:685-693.
[12] 崔海星. 聚烯烃多层锂电池隔膜专利技术分析[J]. 储能科学与技术, 2018,7(4):758-762. CUI H X. A review of the patents of lithium-ion battery polyolefin multilayer separator[J]. Energy Storage Science and Technology, 2018,7(4):758-762. (in Chinese)
[13] PATHAK P, SRIVASTAVA R R, OJASVI. Assessment of legislation and practices for the sustainable management of waste electrical and electronic equipment in India[J]. Renewable and Sustainable Energy Reviews, 2017, 78:220-232.
[14] 国家知识产权局专利检索及分析系统[DB/OL].[2018-12-01]. http://www.pss-system.gov.cn/sipopublicsearch/portal/index.shtml. Patent Search and Analysis system of State Intellectual Property Office, PRC[DB/OL].[2018-12-01]. http://www.pss-system.gov.cn/sipopublicsearch/portal/index.shtml. (in Chinese)
[15] 中国专利全文数据库(知网版)[DB/OL].[2018-12-01]. http://kns.cnki.net/kns/brief/result.aspx?dbprefix=SCOD. China Patent Full-text Database (CNKI Version)[DB/OL].[2018-12-01]. http://kns.cnki.net/kns/brief/result.aspx?dbprefix=SCOD. (in Chinese)
基金
国家科技部重点专项(2017YFB0403300/2017YFB043305);