锌空燃料电池老化实验研究与机理分析

陈东方; 裴普成; 宋鑫

doi:10.16511/j.cnki.qhdxxb.2020.25.022

PDF(6102 KB)

清华大学学报（自然科学版） ›› 2020, Vol. 60 ›› Issue (11) : 895-901. DOI: 10.16511/j.cnki.qhdxxb.2020.25.022

汽车工程

锌空燃料电池老化实验研究与机理分析

陈东方, 裴普成, 宋鑫

作者信息 +

Aging experimental investigation and mechanism analysis for zinc-air fuel cells

CHEN Dongfang, PEI Pucheng, SONG Xin

Author information +

文章历史 +

摘要

耐久性不足严重制约了锌空燃料电池的商业化发展，对电池的老化特性及机理进行实验研究和分析十分必要。该文基于电池应用时面临的单次稳定运行、长周期连续稳定运行、停机储存和周期性启停循环等主要工况提出了锌空燃料电池的耐久性测试评价方法，开展了老化实验。研究了不同工况下电池的老化特性，并结合实验结果分析了老化机理。最后，从电解液管理、延长空气电极寿命和电池管理3个方面提出了延缓电池老化的方法。实验结果表明：该文提出的耐久性测试评价方法可用于锌空燃料电池的老化特性及耐久性提升方法的研究。

Abstract

The commercial development of zinc-air fuel cells is limited by their lack of durability. A zinc-air fuel cell durability test evaluation method was developed based on the working conditions for short term stable operation, long term continuous stable operation, shutdown storage and periodic start-stop cycles. The aging characteristics of zinc-air fuel cells were then experimentally investigated for various operating conditions to study the aging mechanism. Finally, several methods were developed to slow the aging through electrolyte management, methods to extend the air cathode lifetime, and zinc-air fuel cell management. The durability test evaluation method presented in this paper can be used to study the aging characteristics and durability of zinc-air fuel cells.

导出引用

陈东方, 裴普成, 宋鑫. 锌空燃料电池老化实验研究与机理分析[J]. 清华大学学报（自然科学版）. 2020, 60(11): 895-901 https://doi.org/10.16511/j.cnki.qhdxxb.2020.25.022

CHEN Dongfang, PEI Pucheng, SONG Xin. Aging experimental investigation and mechanism analysis for zinc-air fuel cells[J]. Journal of Tsinghua University(Science and Technology). 2020, 60(11): 895-901 https://doi.org/10.16511/j.cnki.qhdxxb.2020.25.022

参考文献

[1] KIM H, JEONG G, KIM Y U, et al. Metallic anodes for next generation secondary batteries[J]. Chemical Society Reviews, 2013, 42(23):9011-9034.
[2] LEE J S, TAI KIM S, CAO R G, et al. Metal-air batteries with high energy density:Li-air versus Zn-air[J]. Advanced Energy Materials, 2011, 1(1):34-50.
[3] XU N N, LI X M, LI H R, et al. A novel composite (FMC) to serve as a durable 3D-clam-shaped bifunctional cathode catalyst for both primary and rechargeable zinc-air batteries[J]. Science Bulletin, 2017, 62(17):1216-1226.
[4] YANG D, TAN H T, RUI X H, et al. Electrode materials for rechargeable zinc-ion and zinc-air batteries:Current status and future perspectives[J]. Electrochemical Energy Reviews, 2019, 2(3):395-427.
[5] 王希忠, 姜智红, 刘伯文, 等. 车用锌空燃料电池系统开发研究[J]. 清华大学学报(自然科学版), 2013, 53(8):1150-1154. WANG X Z, JIANG Z H, LIU B W, et al. Developing a zinc-air fuel cell system for vehicle applications[J]. Journal of Tsinghua University (Science and Technology), 2013, 53(8):1150-1154. (in Chinese)
[6] CHENG F Y, CHEN J. Metal-air batteries:From oxygen reduction electrochemistry to cathode catalysts[J]. Chemical Society Reviews, 2012, 41(6):2172-2192.
[7] WANG K L, PEI P C, WANG Y C, et al. Advanced rechargeable zinc-air battery with parameter optimization[J]. Applied Energy, 2018, 225:848-856.
[8] XU N N, LIU Y Y, ZHANG X, et al. Self-assembly formation of Bi-functional Co₃O₄/MnO₂-CNTs hybrid catalysts for achieving both high energy/power density and cyclic ability of rechargeable zinc-air battery[J]. Scientific Reports, 2016, 6:33590.
[9] PEI P C, MA Z, WANG K L, et al. High performance zinc air fuel cell stack[J]. Journal of Power Sources, 2014, 249:13-20.
[10] SMEDLEY S I, ZHANG X G. A regenerative zinc-air fuel cell[J]. Journal of Power Sources, 2007, 165(2):897-904.
[11] YI J, LIANG P C, LIU X Y, et al. Challenges, mitigationstrategies and perspectives in development of zinc-electrode materials and fabrication for rechargeable zinc-air batteries[J]. Energy & Environmental Science, 2018, 11(11):3075-3095.
[12] FU J, LIANG R L, LIU G H, et al. Recent progress in electrically rechargeable zinc-air batteries[J]. Advanced Materials, 2019, 31(31):e1805230.
[13] DAVARI E, IVEY D G. Bifunctional electrocatalysts for Zn-air batteries[J]. Sustainable Energy & Fuels, 2018, 2(1):39-67.
[14] JIRATCHAYAMAETHASAKUL C, SRIJAROENPRAMONG N, BUNYANGYUEN T, et al. Effects of anode orientation and flow channel design on performance of refuelable zinc-air fuel cells[J]. Journal of Applied Electrochemistry, 2014, 44(11):1205-1218.
[15] NEBURCHILOV V, WANG H J, MARTIN J J, et al. A review on air cathodes for zinc-air fuel cells[J]. Journal of Power Sources, 2010, 195(5):1271-1291.
[16] 马泽. 锌空气燃料电池性能影响因素及性能衰减机理研究[D]. 北京:清华大学, 2015. MA Z. Research on the influence factor of zinc air fuel cell stack and performance degradation mechanism[D]. Beijing:Tsinghua University, 2015. (in Chinese)
[17] MA Z, PEI P C, WANG K L, et al. Degradation characteristics of air cathode in zinc air fuel cells[J]. Journal of Power Sources, 2015, 274:56-64.
[18] WANG Y J, FANG B Z, ZHANG D, et al. A review of carbon-composited materials as air-electrode bifunctional electrocatalysts for metal-air batteries[J]. Electrochemical Energy Reviews, 2018, 1(1):1-34.
[19] SAPKOTA P, KIM H. Zinc-air fuel cell, a potential candidate for alternative energy[J]. Journal of Industrial and Engineering Chemistry, 2009, 15(4):445-450.
[20] HOPKINS B J, SHAO-HORN Y, HART D P. Suppressing corrosion in primary aluminum-air batteries via oil displacement[J]. Science, 2018, 362(6415):658-661.

基金

裴普成,教授,E-mail:pchpei@mail.tsinghua.edu.cn

PDF(6102 KB)

Accesses

Citation

Detail

段落导航

收稿日期	出版日期
2019-09-27	2020-11-15
发布日期
2020-08-31

选择文件类型/文献管理软件名称

选择包含的内容

摘要

Abstract

关键词

Key words

引用本文

{{custom_sec.title}}

{{custom_sec.title}}

参考文献

基金

访问统计

模态框（Modal）标题

选择文件类型/文献管理软件名称

选择包含的内容

摘要

Abstract

关键词

Key words

引用本文

{{custom_sec.title}}

{{custom_sec.title}}

参考文献

基金

访问统计