PDF(9688 KB)
Pyrolytic combustion and fire hazard of ABS materials
Siyuan MU, Quanyi LIU, Ruxuan YANG, Yi LIU, Rui YANG
Journal of Tsinghua University(Science and Technology) ›› 2025, Vol. 65 ›› Issue (7) : 1368-1376.
PDF(9688 KB)
PDF(9688 KB)
Pyrolytic combustion and fire hazard of ABS materials
Objective: Due to the high flammability of nonflame-retardant pure acrylonitrile-butadiene-styrene (ABS), a material often used for passenger luggage, it is easily ignited by open flames, posing risks to aviation operations. Therefore, in-depth research on the pyrolytic combustion characteristics of ABS at high temperatures and high radiation intensities is crucial for the safe operation of aircraft. Methods: This study evaluated the thermal stability and combustion characteristics of ABS under different heating rates and radiation intensity conditions using thermogravimetric analysis and cone calorimeter systems. This study also analyzed the variations in the characteristic parameters of ABS. Results: The results show that the pyrolysis process of ABS can be divided into an initial volatilization stage, a rapid decomposition stage, a residual combustion stage, and a pyrolysis termination stage. In the rapid decomposition stage, when ABS reaches temperatures of approximately 310 ℃ to 343 ℃, the main polymer chains of ABS undergo cleavage, breaking down into different components, such as acrylonitrile and polyethylene monomers, leading to the decomposition of polymer molecules. When heated, the main chain of ABS ruptures. The molecular structure of ABS contains different components, such as styrene and butadiene, which are prone to decomposition and cross-linking reactions upon heating, resulting in the occurrence of the pyrolysis process. An increase in heating rate significantly shortens the pyrolysis time and enhances the maximum thermal decomposition rate. As the radiation intensity increases, the combustion process of ABS accelerates, with the heat release rate increasing and the peak heat release rate increasing by 53%. The combustion and ignition times decrease by 32% and 78%, respectively, because of the increase in material temperature and the exacerbation of heat conduction and convection phenomena leading to an increase in heat release rate. Under low radiation intensities, ABS cannot rapidly absorb energy to reach combustion conditions. However, as the radiation intensity increases, ABS can rapidly absorb sufficient energy for faster decomposition, thus shortening the combustion time. The generation time of carbon monoxide (CO) and carbon dioxide (CO2) is enhanced, and the maximum generation amounts of CO2 and CO increase by 49% and 74%, respectively. The oxygen consumption increases and the oxygen consumption rate accelerates due to the intensified molecular motion caused by thermal radiation, leading to a faster reaction with oxygen in the air. The mass loss time is enhanced, the remaining sample mass decreases, and the maximum mass loss rate increases by 53.8%. Based on the thermal penetration model, 2 mm thick ABS material is classified as a thermally thin material, and verification is conducted. Based on the ignition time model, a critical radiative heat flux formula is established, and the critical radiative heat flux is calculated to be 16.255 kW/m2. Finally, according to the fire performance indicators, as the radiation intensity increases, the material combustion rate increases, releasing higher amounts of heat, leading to faster fire growth and development, thereby increasing fire risk. The fire risk of ABS is positively correlated with the radiation intensity. Conclusions: This study concludes that ABS exhibits a high fire risk. This research provides crucial data and practical references on the fire risks associated with ABS material for safe aviation operations.
acrylonitrile-butadiene-styrene(ABS) / pyrolysis / combustion / radiation intensity / fire hazard
| 1 |
贾旭宏, 张晓宇, 代尚沛, 等. 低气压环境典型民机舱内壁板材料燃烧速率研究[J]. 清华大学学报(自然科学版), 2025, 65 (4): 795- 804.
|
| 2 |
张和平, 陆松, 张丹, 等. 飞机防火技术概论[M]. 北京: 科学出版社, 2017: 373- 374.
|
| 3 |
徐永田, 毛海林, 陈仁辉, 等. ABS树脂热氧分解历程研究[J]. 合成树脂及塑料, 2021, 38 (4): 15- 17.
|
| 4 |
罗婧, 廖厚琪, 潘梦远, 等. 丙烯腈-丁二烯-苯乙烯共聚物和聚乙烯的热解特性及动力学[J]. 武汉工程大学学报, 2016, 38 (1): 17- 23.
|
| 5 |
陈烈强, 王保玉, 梁超, 等. 废旧家电塑料ABS的热解动力学分析[J]. 合成材料老化与应用, 2008, 37 (4): 5- 9.
|
| 6 |
任小男. 丙烯腈-丁二烯-苯乙烯共聚物及其纳米复合材料的热解火蔓延特性及毒性研究[D]. 合肥: 中国科学技术大学, 2016.
REN X N. Investigation of pyrolysis, flame spread and toxicity of acrylonitrile butadiene styrene copolymer and its nanocomposites[D]. Hefei: University of Science and Technology of China, 2016. (in Chinese)
|
| 7 |
王东辉, 刘全义, 李泽锟, 等. 不同热辐射强度下聚碳酸酯的燃烧性能研究[J]. 塑料科技, 2020, 48 (10): 13- 16.
|
| 8 |
刘全义, 马凯庆, 魏超越, 等. 民航客机货舱侧壁板玻纤酚醛复合材料燃烧特性研究[J]. 消防科学与技术, 2023, 42 (4): 454- 458.
|
| 9 |
吴楠, 杨锐, 张辉. 基于局部信息的建筑火灾火源参数反演研究[J]. 中国安全科学学报, 2014, 24 (5): 51- 55.
|
| 10 |
|
| 11 |
|
| 12 |
|
| 13 |
徐亮. 可燃建筑材料火灾危险性综合评价指标[J]. 消防科学与技术, 2016, 35 (7): 1016- 1019.
|
| 14 |
刘秀玉, 张冰, 韩祥祥, 等. 空心玻璃微珠/硬质聚氨酯泡沫复合材料的制备及性能[J]. 复合材料学报, 2020, 37 (9): 2094- 2104.
|
| 15 |
袁春燕, 谷彦鹏, 李明倩, 等. 低热辐射强度下古建筑木构件材料的燃烧特性[J]. 消防科学与技术, 2022, 41 (8): 1046- 1051.
|
| 16 |
舒中俊, 徐晓楠, 杨守生, 等. 基于锥形量热仪试验的聚合物材料火灾危险评价研究[J]. 高分子通报, 2006 (5): 37-44, 78.
|
/
| 〈 |
|
〉 |