Pyrolytic combustion and fire hazard of ABS materials

Siyuan MU, Quanyi LIU, Ruxuan YANG, Yi LIU, Rui YANG

Journal of Tsinghua University(Science and Technology) ›› 2025, Vol. 65 ›› Issue (7) : 1368-1376.

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Journal of Tsinghua University(Science and Technology) ›› 2025, Vol. 65 ›› Issue (7) : 1368-1376. DOI: 10.16511/j.cnki.qhdxxb.2025.22.001
Safety Science

Pyrolytic combustion and fire hazard of ABS materials

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Abstract

Objective: Due to the high flammability of nonflame-retardant pure acrylonitrile-butadiene-styrene (ABS), a material often used for passenger luggage, it is easily ignited by open flames, posing risks to aviation operations. Therefore, in-depth research on the pyrolytic combustion characteristics of ABS at high temperatures and high radiation intensities is crucial for the safe operation of aircraft. Methods: This study evaluated the thermal stability and combustion characteristics of ABS under different heating rates and radiation intensity conditions using thermogravimetric analysis and cone calorimeter systems. This study also analyzed the variations in the characteristic parameters of ABS. Results: The results show that the pyrolysis process of ABS can be divided into an initial volatilization stage, a rapid decomposition stage, a residual combustion stage, and a pyrolysis termination stage. In the rapid decomposition stage, when ABS reaches temperatures of approximately 310 ℃ to 343 ℃, the main polymer chains of ABS undergo cleavage, breaking down into different components, such as acrylonitrile and polyethylene monomers, leading to the decomposition of polymer molecules. When heated, the main chain of ABS ruptures. The molecular structure of ABS contains different components, such as styrene and butadiene, which are prone to decomposition and cross-linking reactions upon heating, resulting in the occurrence of the pyrolysis process. An increase in heating rate significantly shortens the pyrolysis time and enhances the maximum thermal decomposition rate. As the radiation intensity increases, the combustion process of ABS accelerates, with the heat release rate increasing and the peak heat release rate increasing by 53%. The combustion and ignition times decrease by 32% and 78%, respectively, because of the increase in material temperature and the exacerbation of heat conduction and convection phenomena leading to an increase in heat release rate. Under low radiation intensities, ABS cannot rapidly absorb energy to reach combustion conditions. However, as the radiation intensity increases, ABS can rapidly absorb sufficient energy for faster decomposition, thus shortening the combustion time. The generation time of carbon monoxide (CO) and carbon dioxide (CO2) is enhanced, and the maximum generation amounts of CO2 and CO increase by 49% and 74%, respectively. The oxygen consumption increases and the oxygen consumption rate accelerates due to the intensified molecular motion caused by thermal radiation, leading to a faster reaction with oxygen in the air. The mass loss time is enhanced, the remaining sample mass decreases, and the maximum mass loss rate increases by 53.8%. Based on the thermal penetration model, 2 mm thick ABS material is classified as a thermally thin material, and verification is conducted. Based on the ignition time model, a critical radiative heat flux formula is established, and the critical radiative heat flux is calculated to be 16.255 kW/m2. Finally, according to the fire performance indicators, as the radiation intensity increases, the material combustion rate increases, releasing higher amounts of heat, leading to faster fire growth and development, thereby increasing fire risk. The fire risk of ABS is positively correlated with the radiation intensity. Conclusions: This study concludes that ABS exhibits a high fire risk. This research provides crucial data and practical references on the fire risks associated with ABS material for safe aviation operations.

Key words

acrylonitrile-butadiene-styrene(ABS) / pyrolysis / combustion / radiation intensity / fire hazard

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Siyuan MU , Quanyi LIU , Ruxuan YANG , et al . Pyrolytic combustion and fire hazard of ABS materials[J]. Journal of Tsinghua University(Science and Technology). 2025, 65(7): 1368-1376 https://doi.org/10.16511/j.cnki.qhdxxb.2025.22.001

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