基于纤维集合体的化学机械抛光过程分析模型

张瀚升, 张振宇, 赵枫, 石春景, 于志斌, 张帅

清华大学学报(自然科学版) ›› 2025, Vol. 65 ›› Issue (2) : 350-363.

PDF(31997 KB)
PDF(31997 KB)
清华大学学报(自然科学版) ›› 2025, Vol. 65 ›› Issue (2) : 350-363. DOI: 10.16511/j.cnki.qhdxxb.2025.21.003
温诗铸院士纪念专刊

基于纤维集合体的化学机械抛光过程分析模型

作者信息 +

Analysis model of chemical mechanical polishing process based on fiber aggregates

Author information +
文章历史 +

摘要

为深入理解抛光过程中抛光垫纤维结构、抛光液与工件间的相互作用机制, 该文构建了一种流-固耦合分析框架。通过综合实验验证与数值建模两大路径, 系统评估了有序平纹和无序非织造布抛光垫在抛光效能上的差异。针对熔融石英材料的超精密加工需求, 特制了一种绿色环保的抛光液, 其配方融合了氧化铈磨料、过氧化氢及瓜尔胶成分, 并在不同纹理的抛光垫(平纹与非织造布)上进行了应用测试。实验结果显示, 采用非织造布抛光垫的抛光后表面粗糙度Sa低至0.181 nm, 显著优于平纹抛光垫的0.486 nm; 同时, 前者导致的亚表面损伤层厚度也大幅减少至4.14 nm, 仅为后者的1/3(约12.12 nm)。进一步, 流-固耦合模型分析揭示, 非织造抛光垫在抛光过程中展现出更为均匀的纤维应力分布, 最大应力值仅约0.5 MPa, 远低于平纹抛光垫的6 MPa; 此外, 抛光液中的应力分布也趋于均匀, 这一特性优化了整体抛光系统内应力的传递与扩散效率, 促进了材料的均匀去除。综上所述, 本文不仅从实验与数值双重维度凸显了无序非织造抛光系统在熔融石英超精密加工领域的优越性, 更为纤维集合体抛光垫、抛光液与工件间复杂抛光系统的分析、设计乃至制造实践开辟了新的思路与方法。

Abstract

Objective: Chemical mechanical polishing (CMP) is an ultra-precision machining technology for hard and brittle materials. The technology has garnered significant attention from researchers worldwide owing to its low cost of processing equipment and relatively simple operational process. In the CMP process, the polishing pad plays a critical role. It not only serves as the medium for storing the polishing slurry and abrasive particles but also transfers the processing load. This paper presents a fluid-structure coupling analysis framework to elucidate the fiber structure of the polishing pad and the interaction mechanism between the polishing slurry and the workpiece during the polishing process. Methods: An innovative fluid-structure coupling analysis framework is proposed to investigate the interaction mechanism between the fiber structure of the polishing pad, the slurry, and the workpiece during the polishing process. Through comprehensive experimental verification and numerical modeling, the polishing efficiency differences between the ordered plain weave polishing pad and the disordered nonwoven polishing pad were systematically evaluated. To meet the ultra-precision processing requirements of fused silica materials, a green and environmentally friendly polishing slurry was specially developed. The slurry consisted of cerium oxide abrasive, hydrogen peroxide, guar gum, and deionized water. The composition of the polishing slurry and the polishing process were optimized through a single-factor test. Subsequent experiments were conducted on polishing pads with different textures (ordered plain weave fabric and disordered nonwovens) using the optimized slurry and process. The experimental procedure was further optimized through a single-factor test. Results: The experimental results showed that the surface roughness (Sa) of the nonwoven polishing pad was as low as 0.181 nm, which was significantly better than that of the plain weave pad (0.486 nm). In addition, the thickness of the subsurface damage layer caused by the nonwoven pad was reduced to 4.14 nm, approximately one-third of that of the plain weave pad (about 12.12 nm). A comparison of the surface elements of fused silica before and after polishing revealed that the polished sample had no impurity residue on the surface after cleaning. The difference in fiber structure between the two polishing pads only affected mechanical removal during the polishing process but did not influence the chemical reaction. Furthermore, the fluid-structure coupling model analysis revealed that the nonwoven polishing pad exhibited a more uniform fiber stress distribution during polishing, with the maximum stress value being only about 0.5 MPa, considerably lower than the 6 MPa observed for the plain weave pad. In addition, the stress distribution of the slurry in the system was more random and uniform, which optimized the stress transfer and diffusion efficiency throughout the overall polishing system and promoted uniform material removal. Conclusions: In conclusion, this paper highlights the advantages of the disordered nonwoven polishing system in the precision processing of fused silica from both experimental and numerical perspectives. It also provides valuable insights for the analysis, design, and manufacturing practices of complex polishing systems involving fiber aggregate polishing pads, slurry, and workpieces.

关键词

化学机械抛光机理 / 有序平纹抛光垫 / 无序非织造抛光垫 / 数值分析模型 / 原子级表面

Key words

chemical mechanical polishing mechanism / ordered plain weave fabric polishing pad / disordered nonwoven polishing pad / numerical analysis model / atomic surface

引用本文

导出引用
张瀚升, 张振宇, 赵枫, . 基于纤维集合体的化学机械抛光过程分析模型[J]. 清华大学学报(自然科学版). 2025, 65(2): 350-363 https://doi.org/10.16511/j.cnki.qhdxxb.2025.21.003
Hansheng ZHANG, Zhenyu ZHANG, Feng ZHAO, et al. Analysis model of chemical mechanical polishing process based on fiber aggregates[J]. Journal of Tsinghua University(Science and Technology). 2025, 65(2): 350-363 https://doi.org/10.16511/j.cnki.qhdxxb.2025.21.003
中图分类号: TQ171.731   

参考文献

1
SUN H G , ZHANG Z Y , ZENG Z N , et al. Atomic level surface on aspheric quartz crucible with large sizes induced by developed green chemical mechanical polishing with composite rare earth oxides[J]. Surfaces and Interfaces, 2024, 52, 104924.
2
张念民. 铌酸锂晶体纳米压痕及化学机械抛光研究[D]. 大连: 大连理工大学, 2015.
ZHANG N M. Nanoindentation and chemical mechanical polishing of lithium Niobate crystals[D]. Dalian: Dalian University of Technology, 2015. (in Chinese)
3
GUO J , SHI X L , SONG C P , et al. Theoretical and experimental investigation of chemical mechanical polishing of W-Ni-Fe alloy[J]. International Journal of Extreme Manufacturing, 2021, 3 (2): 025103.
4
GUO X G , YUAN S , HUANG J X , et al. Effects of pressure and slurry on removal mechanism during the chemical mechanical polishing of quartz glass using ReaxFF MD[J]. Applied Surface Science, 2020, 505, 144610.
5
ZHANG Z Y , YAN J W , KURIYAGAWA T . Manufacturing technologies toward extreme precision[J]. International Journal of Extreme Manufacturing, 2019, 1 (2): 022001.
6
ZHAO F , ZHANG Z Y , DENG X Q , et al. Atomic surface achieved through a novel cross-scale model from macroscale to nanoscale[J]. Nanoscale, 2024, 16 (5): 2318- 2336.
7
ZHENG J , FANG W C , LI C X , et al. The effect of slurry pH on the chemical mechanical planarization of a carbon-doped Ge2Sb2Te5 phase change material[J]. Journal of Materials Chemistry C, 2022, 10 (44): 16739- 16750.
8
ZHANG J , HONG R C , WANG H . 3D-printed functionally-graded lattice structure with tunable removal characteristics for precision polishing[J]. Additive Manufacturing, 2022, 59, 103152.
9
ZHOU P , SHI H S , WANG L , et al. A quantitative study of removal mechanism of copper polishing based on a single pad-asperity polishing test[J]. International Journal of Mechanical Sciences, 2023, 239, 107878.
10
周海, 王黛萍, 王兵, 等. 抛光垫在蓝宝石衬底化学机械抛光中的应用研究[J]. 机械设计与制造, 2009 (8): 88- 90.
ZHOU H , WANG D P , WANG B , et al. Study the application of pad in chemical mechanical polishing for sapphire wafer[J]. Machinery Design & Manufacture, 2009 (8): 88- 90.
11
ZHANG J Q , ZHANG C H . Material removal model for non-contact chemical mechanical polishing[J]. Chinese Science Bulletin, 2008, 53 (23): 3746- 3752.
12
TSAI M Y , YAN L W . Characteristics of chemical mechanical polishing using graphite impregnated pad[J]. International Journal of Machine Tools and Manufacture, 2010, 50 (12): 1031- 1037.
13
ZHAO F , ZHANG Z Y , ZHOU H X , et al. Novel full-scale model verified by atomic surface and developed composite microfiber and slurry polishing system[J]. Composites Part B: Engineering, 2024, 283, 111598.
14
徐朝阁. 铌酸锂晶体纳米力学及化学机械抛光研究[D]. 大连: 大连理工大学, 2014.
XU C G. Nanomechanics and chemical mechanical polishing of lithium niobate crystals[D]. Dalian: Dalian University of Technology, 2014. (in Chinese)
15
王林. 抛光垫微观接触对化学机械抛光材料去除的影响及其跨尺度建模方法[D]. 大连: 大连理工大学, 2021.
WANG L. Effect of the micro-scale contact status on the material removal process during the chemical mechanical polishing (CMP) and cross-scale modeling of the CMP process[D]. Dalian: Dalian University of Technology, 2021. (in Chinese)
16
GÜRGEN S , SERT A . Polishing operation of a steel bar in a shear thickening fluid medium[J]. Composites Part B: Engineering, 2019, 175, 107127.
17
MU Q , GAO X , YAN Y , et al. Evolution of ring structures and method for inhibition in polishing of fused silica[J]. Applied Surface Science, 2024, 645, 158830.
18
WANG L , ZHOU P , YAN Y , et al. Physically-based modeling of pad-asperity scale chemical-mechanical synergy in chemical mechanical polishing[J]. Tribology International, 2019, 138, 307- 315.
19
WANG L , ZHOU P , YAN Y , et al. Modeling the microscale contact status in chemical mechanical polishing process[J]. International Journal of Mechanical Sciences, 2022, 230, 107559.
20
LING T Y , WANG J , PUI D Y H . Numerical modeling of nanoparticle penetration through personal protective garments[J]. Separation and Purification Technology, 2012, 98, 230- 239.
21
刘东良. 基于准周期性边界条件的复合材料板壳结构等效刚度分析[D]. 大连: 大连理工大学, 2021.
LIU D L. Equivalent stiffness analysis of composite plate and shell structures based on quasi-periodic boundary condition[D]. Dalian: Dalian University of Technology, 2021. (in Chinese)
22
WU L W , ZHAO F , XIE J B , et al. The deformation behaviors and mechanism of weft knitted fabric based on micro-scale virtual fiber model[J]. International Journal of Mechanical Sciences, 2020, 187, 105929.
23
PARK S . Computational modeling for prediction of the shear stress of three-dimensional isotropic and aligned fiber networks[J]. Computer Methods and Programs in Biomedicine, 2017, 148, 91- 98.
24
WU L W , ZHAO F , LU Z Q , et al. Impact energy absorption composites with shear stiffening gel-filled negative Poisson's ratio skeleton by Kirigami method[J]. Composite Structures, 2022, 298, 116009.
25
LIU C , XIE J B , SUN Y , et al. Micro-scale modeling of textile composites based on the virtual fiber embedded models[J]. Composite Structures, 2019, 230, 111552.
26
ZHAO F , WU L W , LU Z Q , et al. Design of shear thickening fluid/polyurethane foam skeleton sandwich composite based on non-Newtonian fluid solid interaction under low-velocity impact[J]. Materials & Design, 2022, 213, 110375.
27
MA W H , LI J H , HOU X . Rolling model analysis of material removal in elastic emission machining[J]. International Journal of Mechanical Sciences, 2023, 258, 108572.
28
CUI X X , ZHANG Z Y , SHI C J , et al. Atomic surface induced by novel green chemical mechanical polishing for aspheric thin-walled crucibles with large diameters[J]. Journal of Manufacturing Processes, 2024, 117, 59- 70.
29
ZHANG Z X , GONG Y , XU J W , et al. Dissecting La2Ce2O7 catalyst to unravel the origin of the surface active sites devoting to its performance for oxidative coupling of methane (OCM)[J]. Catalysis Today, 2022, 400-401, 73- 81.
30
DAVIS K M , TOMOZAWA M . An infrared spectroscopic study of water-related species in silica glasses[J]. Journal of Non-Crystalline Solids, 1996, 201 (3): 177- 198.
31
ZHANG W F , ZHANG P X , LIU F , et al. Simultaneous oxidation of Cr(Ⅲ) and extraction of Cr(Ⅵ) from chromite ore processing residue by silicate-assisted hydrothermal treatment[J]. Chemical Engineering Journal, 2019, 371, 565- 574.
32
HE S , RUAN C C , SHI Y J , et al. Insight to hydrophobic SiO2 encapsulated SiO2 gel: Preparation and application in fire extinguishing[J]. Journal of Hazardous Materials, 2021, 405, 124216.
33
XU G H , ZHANG Z Y , MENG F N , et al. Atomic-scale surface of fused silica induced by chemical mechanical polishing with controlled size spherical ceria abrasives[J]. Journal of Manufacturing Processes, 2023, 85, 783- 792.
34
RITZ M , VALÁŠKOVÁ M . Infrared and Raman spectroscopy of three commercial vermiculites doped with cerium dioxide nanoparticles[J]. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2018, 201, 39- 45.
35
SHI C J , FAN Y H , ZHANG Z Y , et al. Development of core-shell SiO2@A-TiO2 abrasives and novel photocatalytic chemical machinal polishing for atomic surface of fused silica[J]. Applied Surface Science, 2024, 652, 159293.
36
LIU J , ZHANG Z Y , SHI C J , et al. Novel green chemical mechanical polishing of fused silica through designing synergistic CeO2/h-BN abrasives with lubricity[J]. Applied Surface Science, 2023, 637, 157978.
37
LIU Z S , ZHANG Z Y , SUI Y F , et al. Development of mesoporous abrasives and its unprecedented polishing performance elucidated by a novel atomic model[J]. Materials Today Sustainability, 2024, 25, 100700.
38
LI C S , DING J J , ZHANG L C , et al. Densification effects on the fracture in fused silica under Vickers indentation[J]. Ceramics International, 2022, 48 (7): 9330- 9341.
39
KERMOUCHE G , BARTHEL E , VANDEMBROUCQ D , et al. Mechanical modelling of indentation-induced densification in amorphous silica[J]. Acta Materialia, 2008, 56 (13): 3222- 3228.

基金

国家重点研发计划(2018YFA0703400)

版权

版权所有,未经授权,不得转载。
PDF(31997 KB)

Accesses

Citation

Detail

段落导航
相关文章

/